References: The secret is sulphur
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Posted: 1 October 2020 | Bernhard Ringer, Professor Erich Leitner | No comments yet
References for article (Issue 5 2020) in which Erich Leitner and Bernhard Ringer explain importance of sulphur compounds in roasted coffee.
CAS |
Flavour description |
threshold |
concentration |
75-18-3
|
extremely diffusive, repulsive, reminiscent of wild radish, sharp, green, cabbage like; in high dilution bearable, almost acceptable, pleasant, vegetable like
|
vary between 0.3 and 60.0 ppb; 1 ppb and 0. 33 ppb |
0.5-3.5 in roasted coffee and 0.1-3.5 ppm in green coffee (Rhoades 1960); 0.1-0.2 ppm in healthy roasted arabica but 0.8-1.0 ppm in one having a stinking quality by Guyot and Vincent (1990) |
624-92-0
|
intensive onion-like character
|
3 ppb to 7.6 ppb in water and 12 ppb |
0.01 ppm in arabicas and 0.10-0.12 ppm in Robustas by Silwar et al. (1986) 0.04-0.05 ppm in a roasted healthy arabica and 0.3 – 0.4 in the stinking quality by Guyot and Vincent (1990) |
3658-80-8
|
powerful, diffusive, penetrating odour of fresh onion, cabbage, burnt, cooked |
0.01 ppb
|
1 ppb in two arabicas and 0.1 ppm in two other arabicas by Silwar et al 1986 |
74-93-1
|
Rotten cabbage; one of the most intense noted to roasted coffee |
0,02 – 2.1 ppb in water |
1.5-4.3 in roasted coffee and 0.1-0.3 ppm in green coffee by Rhoades 1960 |
5287-45-6
|
pure substance smells pungent or leek like; at 0.1 ppm penetrating animal like, foxy, skunky; at 0.4 ppm skunky, meaty, coffee, fatty, tarry |
0.2-0.4 g/m^3 in air and 0.2 – 0.3 ppt (0.0002-0.0003 µg/L) in water |
8.2 ppb in freshly roasted ground coffee by Grosch (1996)
|
98-02-2
|
classic coffee odor, extremely powerful, diffusive penetration odor, in proper dilution gives coffee-like, caramel-like-burnt, sweet
|
0.04ppb down to 5 ppt
|
1.1 ppm in arabica and 2.0 ppm in Robusta by Tressl and Silwar 1981, similar from Silwar 1986 and Tressl 1989; 1.7 ppm in a Columbian arabica by Grosch et al 1993 and 1.95 ppm in an Indonesian Robusta; 1.08 ppm for an arabica and 1.73 ppm for a Robusta by Semmelroch et al 1995
|
28588-74-1
|
meat like, roasted coffee
|
0.005-0.01 ppb
|
0.148 ppm in a Columbia arabica and 0.195 in a Kenya arabica by Grosch et al 1996
|
3268-49-3
|
powerful, diffusive onion and meat like, in dilution more pleasant, less onion-like, reminiscent of bouillon; at 2 ppm typical meaty and sulfur flavor
|
0.2 ppb in water; and 9 µg/kg in cellulose
|
240 ppb in Columbian arabica and 95 ppb in an Indonesia Robusta Semmelroch et al. 1995 ; 22 ppb in green arabica and 213 ppb after roasting Czerny and Grosch 2000 |
50746-10-6 |
sweaty, fruity odor, becoming black currant and catty in aqueous solution at 0. 1 ppm; penetrating sweaty and catty; belong to the most potent odors; at 0.1 ppm tropical, fruit, green, sulfur, hop flavor and black currant, leaves, clary sage and orange flowers; in great dilution in a coffee beverage roast coffee likeness
|
2-5 ppt odor thresholds and 5-8 ppt taste threshold; 3 * 10-4 µg/m3 in air and 3.5 ppt in water |
0.13 ppm in arabica and 0.115 ppm in Robusta by Semmelroch et al 1995 |
The most important sulphur compounds, their odour thresholds and concentrations in coffee.
Credit: Flament, Ivon; Bessière-Thomas, Yvonne (2002): Coffee flavor chemistry. Chichester, New York: Wiley